Synthesis and properties of new photosensitive triazene and o-nitrobenzene methacrylates

V Gaud, F Rougé, Y Gnanou, JP Desvergne

Index: Gaud, Vincent; Rouge, Fabien; Gnanou, Yves; Desvergne, Jean-Pierre Reactive and Functional Polymers, 2012 , vol. 72, # 8 p. 521 - 532

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Citation Number: 6

Abstract

New photoactive polymerizable monomers were synthesized in order to photomodulate the mechanical properties of photocurable materials. These monomers are end-capped by at least two polymerizable units (using irradiation wavelength λ1) connected by a spacer including at least one photocleavable unit (irradiation wavelength λ2≠ λ1) ie aryltriazene or 2-nitrobenzyl core. The photochemical behaviour of these systems was studied in solution ...