Organic letters

Suzuki-Miyaura reactions of arenediazonium salts catalyzed by Pd (0)/C. One-pot chemoselective double cross-coupling reactions

RH Taylor, FX Felpin

Index: Taylor, Rachel H.; Felpin, Francois-Xavier Organic Letters, 2007 , vol. 9, # 15 p. 2911 - 2914

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Citation Number: 90

Abstract

The Suzuki-Miyaura cross-coupling of arenediazonium tetrafluoroborate salts with boronic acid partners catalyzed by Pd (0)/C is described as a practical and efficient alternative to classical homogeneous conditions. Reactions conducted in alcoholic solvents proved to be extremely fast using mild conditions. Additionnaly, we developed a chemoselective double Suzuki-Miyaura cross-coupling in a single reaction vessel allowing the synthesis of ...