… C–R+ with R= H, D, CD3 and C2H5–C≡ C–C≡ C–R+ with R= H and C2H5. Competition of the radiative à (π− 1)→ X̃ (π− 1) and fragmentation decay of their à (π− 1) …

…, O Marthaler, E Kloster??Jensen

Index: Maier, John P.; Marthaler, Oskar; Kloster-Jensen, Else Journal of Chemical Physics, 1980 , vol. 72, # 1 p. 701 - 708

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Citation Number: 18

Abstract

Optical emission spectra of the radical cations given in the title have been detected in the gaseous phase, using low energyelectrons for the excitation. The band systems are assigned to the à (π− 1)→ X̃ (π− 1) electronic transitions of these cations by reference to the photoelectron spectroscopic data. A vibrational analysis of the emission bands yields the frequencies of some of the totally symmetric fundamentals for the X̃ states and of one or ...