Unsaturated heterocyclic systems. XL. Evaluation of spiro [9, 10-ethanoanthracene-11, 2'-thietane] S, S-dioxides and 2. alpha.-dialkylaminoalkyl-3- …

LA Paquette, M Rosen, H Stucki

Index: Paquette,L.A. et al. Journal of Organic Chemistry, 1968 , vol. 33, p. 3020 - 3027

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Citation Number: 8

Abstract

Results The Retro Diels-Alder Route.-Our initial approach was designed to take advantage of the fact that 9, lO-ethanoanthracene derivatives decompose at somewhat elevated temperatures to generate anthracene and unsaturated compounds. Specifically, the intent was to construct a thiete dioxide derivative which incorporated the partially reduced anthracene ring as a blocking group for the exocyclic double bond. This reactive site of ...