Synthesis, characterization, and formation constant of hexacoordinate iron (III) complexes

…, B Hemmateenejad, M Mohammadikish

Index: Asadi, Mozaffar; Hemmateenejad, Bahram; Mohammadikish, Maryam Journal of Coordination Chemistry, 2010 , vol. 63, # 1 p. 124 - 135

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Citation Number: 5

Abstract

Twelve iron (III) complexes [FeIII (LX) 2] ClO4, where (LX)− is the deprotonated form of a series of asymmetric ligands containing pyridine and substituted phenol moieties (XPh (OH)– CH= N–(CH2) n–Py that X= H, 5-Br, 5-NO2, 5-OMe, 4-OMe, 3-OMe, and n= 1, 2), were synthesized and characterized by 1H NMR, IR, UV-Vis spectroscopy, mass spectrometry, and elemental analysis. Formation constants were measured using UV-Vis ...