The synthesis of two 3, 3, 3-triarylpropenes and two 2-methyl-3, 3, 3-triarylpropenes

ROC Norman, CB Thomas

Index: Norman,R.O.C.; Thomas,C.B. Journal of the Chemical Society [Section] C: Organic, 1967 , p. 1115 - 1120

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Citation Number: 6

Abstract

The syntheses of 2-methyl-3, 3, 3-triphenylpropene and 3, 3, 3-triphenylpropene, and the p- methoxy-derivative of each are described. Notable features are the ready dehydration by phosphoryl chloride in pyridine of two sterically hindered tertiary alcohols which are unaffected by sulphuric or phosphoric acid; the efficiency of the reaction of two triarylmethyl Grignard reagents with ethylene oxide; and the use of aqueous dimethyl sulphoxide as ...