Synthesis

Preparation of 1-alkenes by the palladium-catalyzed hydrogenolysis of terminal allylic carbonates and acetates with formic acid-triethylamine

J Tsuji, I Minami, I Shimizu

Index: Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao Synthesis, 1986 , # 8 p. 623 - 627

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Citation Number: 55

Abstract

Tokyo institute ot" l 'echnology, Meguro. Tokyo 152. Japan/\ useful method for the preparations of 1-alkenes from terminal ullyhc eairbonates and acetates by the palladiuiti- catalyzed reaction with ll! t'lTlill ('S is described. Formie acid-1riethylitmine is a suitable rcduetzznt. As czitztlyst, I'< l;(clbzt), t § llC] 3~—Ptn-Bu) J gave the best results. 0.05 (). 2n1ol", 1. lveing sullieicnt (turnover Silt) 2001)). Using this method. various l'iill\ L'llC $ ...