Rearrangements of organosilicon compounds using organoaluminum reagents. Conversion of phenyl-and alkenyl (chloromethyl) silanes to benzyl-and allylsilanes

PF Hudrlik, YM Abdallah, AK Kulkarni…

Index: Hudrlik, Paul F.; Abdallah, Yousef M.; Kulkarni, Ashok K.; Hudrlik, Anne M. Journal of Organic Chemistry, 1992 , vol. 57, # 24 p. 6552 - 6556

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Citation Number: 22

Abstract

PhMerSiLi pounds, with migration of an organic group from silicon to carbon, have been known for some time, but have been studied very little from a synthetic point of view.'These rearrangements have been found to take place under the influence of nucleophiles, B and heat.'Initially