[1] Molybdarenophanes: Strained metallarenophanes with aluminum, gallium, and silicon in bridging positions

…, JA Schachner, JW Quail, J Müller

Index: Lund, Clinton L.; Schachner, Joerg A.; Quail, J. Wilson; Mueller, Jens Journal of the American Chemical Society, 2007 , vol. 129, # 30 p. 9313 - 9320

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Citation Number: 39

Abstract

The first [1] molybdarenophanes were synthesized and structurally characterized. The aluminum and gallium compounds [(Me2Ntsi) Al (η6-C6H5) 2Mo](2a) and [(Me2Ntsi) Ga (η6- C6H5) 2Mo](2b)[Me2Ntsi= C (SiMe3) 2 (SiMe2NMe2)] were obtained from [Mo (LiC6H5) 2]⊙ TMEDA and (Me2Ntsi) ECl2 [E= Al, Ga] in analytical pure form with isolated yields of 74%(2a) and 52%(2b). The silicon-bridged species [Ph2Si (η6-C6H5) 2Mo](2c) was ...