Reversible reaction of dioxygen (and carbon monoxide) with a copper (I) complex. X-ray structures of relevant mononuclear Cu (I) precursor adducts and the trans-(. …

…, N Wei, NN Murthy, J Zubieta, KD Karlin

Index: Tyeklar, Zoltan; Jacobson, Richard R.; Wei, Ning; Murthy, Narasappa Narasimha; Zubieta, Jon; Karlin, Kenneth D. Journal of the American Chemical Society, 1993 , vol. 115, # 7 p. 2677 - 2689

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Citation Number: 415

Abstract

Abstract: The study of copper4ioxygen interactions and reactivity is of interest in chemical systems which involve redox activity or oxidative transformations and in biological systems where copper proteins are known to effect a variety of functions including dioxygen transport, substrate oxygenation, and 02 reduction. Here, we describe reactions of 0 2 (and CO) with a mononuclear copper (1) complex containing a tripodal tetradentate ligand L ( ...