Inorganic Chemistry

Synthesis and reaction chemistry of the coordinatively unsaturated heterobimetallic complexes (CO) 3 (PPh3) Fe (. mu.-PCy2) Rh (PPh3)(CO) and (CO) 4Fe (. mu.- …

HA Jenkins, SJ Loeb, DW Stephan

Index: Jenkins, Hilary A.; Loeb, Stephen J.; Stephan, Douglas W. Inorganic Chemistry, 1989 , vol. 28, p. 1998 - 2003

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Citation Number: 17

Abstract

The diorganophosphide group (PR,) has shown great versatility as a bridging ligand, and it is particularly suited for the synthesis of heterobimetallic comp1exes. l Although numerous studies have produced a variety of interesting metal combinations, 2-'2 there are only a limited number of heterobimetallic complexes that contain easily displaced ligands13-16 or coordinatively unsaturated metal centers2i1s* 16 of the type usually found in reactive ...