NOVEL ANIONIC CHALCOGENO LIGANDS. TELLUROPHOSPHINITES R2PTe-AND CHALCOGENOTELLUROPHOSPHINATES R2P (Ch) Te-[Ch˭ O, S, Se, Te]

B Bildstein, F Sladky

Index: Bildstein, Benno; Sladky, Fritz Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 47, p. 341 - 347

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Citation Number: 13

Abstract

Abstract Elemental tellurium reacts with diorganylphosphides R2P− to give tellurophosphinites R2PTe− and with chalcogenophosphinites R2PCh− to give chalcogenotellurophosphinates R2P (Ch) Te-[R˭ C6H11, C6H5; Ch˭ O, S, Se, Te]. respectively. Borane-or chromium-pentacarbonyl complexed phosphides also react with elemental tellurium to the corresponding tellurophosphinito complexes R2P (BH3) Te-and ...