Tetrahedron letters

Palladium-catalyzed reduction of propargylic acetates with SmI 2. A mild and convenient method for the preparation of allenes

T Tabuchi, J Inanaga, M Yamaguchi

Index: Tabuchi, Takanori; Inanaga, Junji; Yamaguchi, Masaru Tetrahedron Letters, 1986 , vol. 27, # 43 p. 5237 - 5240

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Citation Number: 65

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A highly regioselective reduction of propargylic acetates has been attained by using SmI 2 and catalytic Pd(0) in the presence of 2,4-dimethyl-3-pentanol affording various types of allenes in high yields. ... A new general method for the preparation of allenes from prapargylic ...