Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates

S Biswas, JP Page, KR Dewese…

Index: Huang, Yange; Fananas-Mastral, Martin; Minnaard, Adriaan J.; Feringa, Ben L. Chemical Communications, 2013 , vol. 49, # 32 p. 3309 - 3311

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Abstract

... J. Am. ... Article ASAP. DOI: 10.1021/jacs.5b10364. Publication Date (Web): November 3, 2015. Copyright © 2015 American Chemical Society. *rajanbabu ... reaction that results in the regio- and stereoselective synthesis of a silyl enol ether involves a Rh(L*)-catalyzed enantioselective ...

 Related Synthetic Route
2,4-Hexadienedioicacid, 1,6-dimethyl ester, (2E,4E)- Structure

1119-43-3

2,4-Hexadienedi...

~81%

(2E,4E)-hexa-2,4-diene-1,6-diol Structure

107550-83-4

(2E,4E)-hexa-2,...

5-phenyl-(2E,4E)-pentadienoic acid methyl ester Structure

38447-05-1

5-phenyl-(2E,4E...

~%

hexa-1,3-dienylbenzene Structure

39491-62-8

hexa-1,3-dienyl...

N/A Structure

1021340-56-6

N/A

N/A Structure

1429425-41-1

N/A

(2E)-N-(3-FLUOROPHENYL)-2-(HYDROXYIMINO)ACETAMIDE Structure

58506-33-5

(2E)-N-(3-FLUOR...

~%

hexa-1,3-dienylbenzene Structure

39491-62-8

hexa-1,3-dienyl...

N/A Structure

1021340-56-6

N/A

N/A Structure

1429425-41-1

N/A

METHYLMAGNESIUM BROMIDE Structure

75-16-1

METHYLMAGNESIUM...

((1E,3E)-5-BROMO-PENTA-1,3-DIENYL)-BENZENE Structure

109529-98-8

((1E,3E)-5-BROM...

~%

hexa-1,3-dienylbenzene Structure

39491-62-8

hexa-1,3-dienyl...

N/A Structure

1021340-56-6

N/A

Detail
(2E,4E)-5-phenylpenta-2,4-dienoic acid Structure

28010-12-0

(2E,4E)-5-pheny...

~%

hexa-1,3-dienylbenzene Structure

39491-62-8

hexa-1,3-dienyl...

N/A Structure

1021340-56-6

N/A

N/A Structure

1429425-41-1

N/A

(E)-4,4-Dimethoxy-3-methyl-crotonsaeureaethylester Structure

65527-84-6

(E)-4,4-Dimetho...

~%

ethyl 6-hydroxy-3-methylhexa-2,4-dienoate Structure

88714-53-8

ethyl 6-hydroxy...

Ethyl (E)-3-methyl-4-oxobut-2-enoate Structure

62054-49-3

Ethyl (E)-3-met...

~%

ethyl 6-hydroxy-3-methylhexa-2,4-dienoate Structure

88714-53-8

ethyl 6-hydroxy...

(E)-4,4-Dimethoxy-3-methyl-crotonsaeureaethylester Structure

65527-84-6

(E)-4,4-Dimetho...

~%

ethyl 3-methyl-6-oxohexa-2,4-dienoate Structure

35482-69-0

ethyl 3-methyl-...

(2E,4E)-5-phenylpenta-2,4-dienoic acid Structure

28010-12-0

(2E,4E)-5-pheny...

~%

((1E,3E)-5-BROMO-PENTA-1,3-DIENYL)-BENZENE Structure

109529-98-8

((1E,3E)-5-BROM...

5-phenyl-(2E,4E)-pentadienoic acid methyl ester Structure

38447-05-1

5-phenyl-(2E,4E...

~%

((1E,3E)-5-BROMO-PENTA-1,3-DIENYL)-BENZENE Structure

109529-98-8

((1E,3E)-5-BROM...

Sorbic acid Structure

110-44-1

Sorbic acid

~%

(2E,4E)-Methyl 6-bromohexa-2,4-dienoate Structure

51010-88-9

(2E,4E)-Methyl ...


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