Sulfur (IV)-mediated transformations: from ylide transfer to metal-free arylation of carbonyl compounds

…, M Patil, C Fares, W Thiel, N Maulide

Index: Huang, Xueliang; Goddard, Richard; Maulide, Nuno Chemical Communications, 2013 , vol. 49, # 39 p. 4292 - 4294

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Citation Number: 40

Abstract

The development of a direct ylide transfer to carbonyl derivatives and of a sulfoxide- mediated arylation is presented from a unified perspective. Mechanistic studies (including density functional calculations) support a common reaction pathway and showcase how