Reactions of acetylenes with noble metal carbonyl halides. 9. Preparation, chemical characterization and x-ray structural analysis of [cyclic][Pt {C (O) CPr: CPrCPr: …

L Garlaschelli, MC Malatesta, S Panzeri…

Index: Garlaschelli, Luigi; Malatesta, Maria Carlotta; Panzeri, Silvia; Albinati, Alberto; Ganazzoli, Fabio Organometallics, 1987 , vol. 6, p. 63 - 72

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Citation Number: 17

Abstract

It has been found that several metal carbonyl complexes react with substituted alkynes to produce organic compounds containing both carbon monoxide and alkyne-derived fragments; organometallic complexes containing u-and/or a-bonded cyclic organic systems derived from alkyne fragments with insertion of carbon monoxide groups are also formed? The reaction conditions, such as solvents and temperature, play an important role in ...