Tetrahedron Letters

Synthesis of trichoverrol B

WR Roush, AP Spada

Index: Roush, William R.; Spada, Alfred P. Tetrahedron Letters, 1983 , vol. 24, # 35 p. 3693 - 3696

Full Text: HTML

Citation Number: 27

Abstract

This document does not have an outline. ... JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. ... Author links open the overlay panel. Numbers correspond to the affiliation list which can be exposed by using the show more link. ... A highly diastereoselective synthesis of trichoverrol B (1) is described. Critical to the success of this work is the development of a method for esterification of (Z,E)-dienoic acid derivatives without ...

 Related Synthetic Route
(2S,4'R,5a'R)-5a'-(((4-((tert-butyldimethylsilyl)oxy)butanoyl)oxy)methyl)-5',8'-dimethyl-2',3',4',5',5a',6',7',9a'-octahydrospiro[oxirane-2,10'-[2,5]methanobenzo[b]oxepin]-4'-yl (4E,6S,7R)-6,7-bis((tert-butyldimethylsilyl)oxy)octa-2,4-dienoate Structure

88223-55-6

(2S,4'R,5a'R)-5...

~91%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

((2S,4'R,5a'R)-4'-hydroxy-5',8'-dimethyl-2',3',4',5',7',9a'-hexahydrospiro[oxirane-2,10'-[2,5]methanobenzo[b]oxepin]-5a'(6'H)-yl)methyl 4-((tert-butyldimethylsilyl)oxy)butanoate Structure

88245-09-4

((2S,4'R,5a'R)-...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(4α,12ξ)-12,13-Epoxytrichothec-9-ene-4,15-diol Structure

2198-92-7

(4α,12ξ)-12,13-...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(S)-6-((1S,2R)-2-((tert-butyldimethylsilyl)oxy)-1-hydroxypropyl)tetrahydro-2H-pyran-2-one Structure

88235-44-3

(S)-6-((1S,2R)-...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

N/A Structure

88235-47-6

N/A

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(S)-6-((4S,5R)-2,2,5,7,7,8,8-heptamethyl-3,6-dioxa-2,7-disilanonan-4-yl)-5,6-dihydro-2H-pyran-2-one Structure

88235-48-7

(S)-6-((4S,5R)-...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(2Z,4E,6S,7R)-7-((tert-butyldimethylsilyl)oxy)-6-((trimethylsilyl)oxy)octa-2,4-dienoic pivalic anhydride Structure

88235-50-1

(2Z,4E,6S,7R)-7...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(2Z,4E,6S,7R)-6,7-bis((tert-butyldimethylsilyl)oxy)octa-2,4-dienoic pivalic anhydride Structure

88223-56-7

(2Z,4E,6S,7R)-6...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B

(2Z,4E,6S,7R)-6,7-bis((tert-butyldimethylsilyl)oxy)octa-2,4-dienoic acid Structure

82495-48-5

(2Z,4E,6S,7R)-6...

~%

Trichoverrol B Structure

76685-83-1

Trichoverrol B


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