Practical One??Pot Preparation of Magnesium Di (hetero) aryl??and Magnesium Dialkenylboronates for Suzuki–Miyaura Cross??Coupling Reactions

…, C Sämann, A Jana, P Knochel

Index: Haag, Benjamin A.; Saemann, Christoph; Jana, Anukul; Knochel, Paul Angewandte Chemie - International Edition, 2011 , vol. 50, # 32 p. 7290 - 7294

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Citation Number: 28

Abstract

Arylboron derivatives have found broad applications in Suzuki–Miyaura cross-coupling reactions.[1] In particular, various boronic acids,[2] esters, and their derivatives, such as trifluoroborates,[3] MIDA boronates [4] or DAN reagents,[5] have been used very successfully (MIDA= N-methyliminodiacetic acid, DAN= 2, 3-diaminonaphthalene). In general, most arylboronic compounds are prepared via lithium or magnesium ...