… Bromide-Mediated Cascade Cyclization of Homoallylic Esters. Synthesis of 2-(2-Hydroxyalkyl) cyclopropanols and 2-(2-Hydroxyethyl) bicyclo [2.1. 1] hexan-1-ols

…, H Mao, T Xie, RA Flowers, X Lv, X Wang

Index: Yin, Ruifeng; Zhou, Liejin; Liu, Huili; Mao, Hui; Lue, Xin; Wang, Xiaoxia Chinese Journal of Chemistry, 2013 , vol. 31, # 1 p. 143 - 148

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Abstract

In continuation of our previous study on the intramolecular reductive coupling of simple homoallylic esters promoted by allylSmBr/HMPA/H2O, which afforded a facile synthesis of 2- (2-hydroxyalkyl) cyclopropanols, here we report the reductive cascade cyclization of but-3-