Covalently Linked Ruthenium (II)− Manganese (II) Complexes: Distance Dependence of Quenching and Electron Transfer

…, S Styring, L Hammarström, H Toftlund…

Index: Berg, Katja E.; Tran, Anh; Raymond, Mary Katherine; Abrahamsson, Malin; Wolny, Juliusz; Redon, Sophie; Andersson, Mikael; Sun, Licheng; Styring, Stenbjoern; Hammarstroem, Leif; Toftlund, Hans; Akermark, Bjoern European Journal of Inorganic Chemistry, 2001 , # 4 p. 1019 - 1029

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Citation Number: 56

Abstract

Abstract Continuing our development of artificial models for photosystem II in green plants, a series of compounds have been prepared in which a Ru (bpy) 3 2+ photosensitizer is covalently linked to a manganese (II) electron donor. In addition to a trispicolylamine ligand, two other manganese ligands, dipicolylamine and aminodiacetic acid, have been introduced in order to study ligands that are appropriate for the construction of manganese dimers ...