Russian journal of general chemistry

3-and 4-dialkoxyphosphorylmethyl derivatives of 5-tert-butylfuran with electron-withdrawing substituents in position 2

LM Pevzner

Index: Pevzner Russian Journal of General Chemistry, 2003 , vol. 73, # 11 p. 1715 - 1724

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Abstract

Abstract A procedure for preparing 3-, 4-halomethyl derivatives of 5-tert-butylfuran containing elec-tron-withdrawing substituents in position 2 was developed, and phosphorylation of the resulting productsunder the conditions of the Arbuzov and Michaelis- Becker reactions was studied. 3-Bromomethyl derivatives are phosphorylated with trimethyl phosphite considerably faster than their 4-chloromethyl analogs. At the same time, 3-and ...