A helical chiral polymer??based chromo??fluorescence and CD response sensor for selective detection of trivalent cations

L Wang, F Li, X Liu, G Wei, Y Cheng…

Index: Wang, Lu; Li, Fei; Liu, Xunhua; Wei, Guo; Cheng, Yixiang; Zhu, Chengjian Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 19 p. 4070 - 4075

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Citation Number: 9

Abstract

ABSTRACT A novel chiral (S)-BINAM-based fluorescent polymer sensor was designed and synthesized by the polymerization of 4, 4′-((2, 5-dibutoxy-1, 4-phenylene) bis (ethyne-2, 1- diyl))-dibenzaldehyde (M-1) with (S)-2, 2′-binaphthyldiamine (S-BINAM, M-2) via Schiff's base formation. The resulting helical chiral polymer sensor exhibited remarkable “turn-on” bright blue fluorescence color upon the addition of trivalent metal ions under a ...