Two new unsymmetrical squaraines (WCH-SQ10 and WCH-SQ11), wherein the electron- rich 3, 4-ethylenedioxy-thiophene conjugated fragment was linked unconventionally to the squaraine core and triphenyl amine donor, and carboxylic acid substituted quinoline was used as an acceptor, were prepared. WCH-SQ10 and WCH-SQ11 dyes in ethanol have the λmax of 686 and 673 nm, respectively. The corresponding photovoltaic devices exhibit an ...