Photoreaction of (p-nitrophenyl) glyoxylic acid to p-nitrosobenzoic acid in aqueous solution

H Goerner, LJ Currell, HJ Kuhn

Index: Goerner, Helmut; Currell, Leslie J.; Kuhn, Hans Jochen Journal of Physical Chemistry, 1991 , vol. 95, # 14 p. 5518 - 5523

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Citation Number: 7

Abstract

Max-Planck-instirut fiir Strahlenchemie. 0-4330 Mtilheim an der Ruhr, Germany (Received: December 28, 1990; In Final Form: February 26, 1991)(pNitropheny1) glyoxylic acid (NO2- PA) was studied by time-resolved and steady-state photochemical methods in water and mixtures with acetonitrile at room temperature. Irradiation of NO2-PA leads to pnitrosobenzoic acid (NO-BA) and C02 in substantial yield (@= 0.28 in aqueous solution ...