Application of chiral mixed phosphorus/sulfur ligands to palladium-catalyzed allylic substitutions

DA Evans, KR Campos, JS Tedrow…

Index: Matt, Thomas; Seebach, Dieter Helvetica Chimica Acta, 1998 , vol. 81, # 10 p. 1845 - 1895

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Citation Number: 284

Abstract

... Volume: Page: Digital Object Identifier (DOI). ... P/N and N/S Ligands. ... 10 He attributed the erosion of reaction enantioselectivity to sulfur inversion which was detected by 1 H NMR spectroscopy on the complex [Pd(C 3 H 5 )(F)](OTf). ...