Copper (II)??Catalyzed Aromatization Followed by Bromination of Cyclohexenones Leading to Phenols and Bromophenols

HC Tong, KR Reddy, ST Liu

Index: Tong, Hung-Chun; Reddy, K. Rajender; Liu, Shiuh-Tzung European Journal of Organic Chemistry, 2014 , vol. 2014, # 15 p. 3256 - 3261

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Abstract

Abstract Conversion of substituted cyclohexenones into the corresponding phenols can be achieved using copper acetate as the catalyst in the presence of LiBr and CF 3 COOH under oxygen. With the use of excess LiBr, electrophilic aromatic bromination afforded the corresponding bromophenol under similar catalytic conditions.