The Journal of Organic Chemistry

Preparation of tertiary N, N-dimethylamines by the leuckart reaction

RD Bach

Index: Bach,R.D. Journal of Organic Chemistry, 1968 , vol. 33, p. 1647 - 1649

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Citation Number: 30

Abstract

Vol. $3, No. 4, April 1968 NOTES 1647. lnal. Calcd for C~~ HZ~ NO~: C, 62.36; H, 4.95; N, 2.91; mol wt, 481. Found: C, 62.40; H, 5.08; N, 2.82. Condensation of Oxazolone 6 with Dimethyl 3-0xoglutarate.-In a manner identical with that described for the reaction of oxazolone 5, 878 mg (2.74 mmol) of 6 was allowed to react with 570 mg (3.28 mmol) cf dimethyl 3-oxoglutarate and 75.5 mg (3.15 mmol) of sodium hydride. A yield of 1.27 g of a ...