Synthesis and electrochemistry of late transition metal complexes containing 1, 1′-bis (dicyclohexylphosphino) ferrocene (dcpf). The X-ray structure of [PdCl 2 (dcpf)] …

…, AN Campbell, JA Golen, AL Rheingold…

Index: Hagopian, Laura E.; Campbell, Alison N.; Golen, James A.; Rheingold, Arnold L.; Nataro, Chip Journal of Organometallic Chemistry, 2006 , vol. 691, # 23 p. 4890 - 4900

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Citation Number: 39

Abstract

The electrochemistry of 1, 1′-bis (dicyclohexylylphosphino) ferrocene (dcpf) was examined in methylene chloride with tetrabutylammonium hexafluorophosphate or tetrabutylammonium tetrakis (pentafluorophenyl) borate as the supporting electrolyte. The oxidation of dcpf is complicated by a follow-up reaction. Seven new complexes containing dcpf and one new compound containing 1, 1′-bis (di-tert-butylphosphino) ferrocene ( ...