Analytical chemistry

Synthesis, characterization, and application of chiral ionic liquids and their polymers in micellar electrokinetic chromatography

SAA Rizvi, SA Shamsi

Index: Rizvi, Syed Asad Ali; Shamsi, Shahab A. Analytical Chemistry, 2006 , vol. 78, # 19 p. 7061 - 7069

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Citation Number: 141

Abstract

Two amino acid-derived (leucinol and N-methylpyrrolidinol) chiral ionic liquids are synthesized and characterized in both monomeric and polymeric forms. Leucinol-based chiral cationic surfactant is a room-temperature ionic liquid, and pyrrolidinol-based chiral cationic surfactant melts at 30-35° C to form an ionic liquid (IL). The monomeric and polymeric ILs are thoroughly characterized to determine critical micelle concentration, ...

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