… of partially oxidized metallamacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Chemical and architectural properties …

…, T Inabe, KF Schoch Jr, TJ Marks

Index: Dirk, Carl W.; Inabe, Tamotsu; Schoch, Karl F.; Marks, Tobin J. Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1539 - 1550

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Citation Number: 271

Abstract

Abstract: This contribution reports a detailed chemical, spectroscopic, and X-ray diffractometric study of the nature and structures of the cofacially joined metallomacrocyclic polymers [M (Pc) O],, where M= Si, Ge, Sn and Pc= phthalocyaninato. These materials are precursors for a new class of electrically conductive polymers. Improved syntheses of the polymers are first reported. Optical spectra are assigned within the context of a porphyrinic ...