Journal of Carbohydrate Chemistry

N-Bromosuccinimide-Mediated Conversion of Allyl Glycosides to Glycosyl Hemiacetals

R Panchadhayee, AK Misra

Index: Panchadhayee, Rajib; Misra, Anup Kumar Journal of Carbohydrate Chemistry, 2010 , vol. 29, # 2 p. 76 - 83

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Citation Number: 5

Abstract

A novel reaction condition has been developed for the hydrolysis of differentially functionalized allyl glycosides to their corresponding glycosyl hemiacetal derivatives in the presence of N-bromosuccinimide (NBS). The reaction condition is exceptionally fast, mild, and compatible with most of the functional groups used in the oligosaccharide synthesis, and yields were excellent.