Tetrahedron

Unexpected formation of aryl dialkyl carbinol as a side product from the reaction of methoxyarylaldehydes with Grignard reagents

A Sharma, BP Joshi, NP Singh, AK Sinha

Index: Tetrahedron, , vol. 62, # 5 p. 847 - 851

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Citation Number: 9

Abstract

... Tetrahedron. Volume 62, Issue 5, 30 January 2006, Pages 847–851. ... White solid, 3.1 g (12%); mp 60–62 °C; ν max (CHCl 3 ) 3571 cm −1 ; 1 H NMR (CDCl 3 , 300 MHz): δ 6.52 (2H, s, H-2 and H-6), 3.78 (9H, s, 3,4,5-OCH 3 ), 1.76 (4H, q, J=6.85 Hz, H-2′ and H-2′), 0.73 (6H, t ...