Mass spectrometry in structural and stereochemical problems. CLXXXI. Remote group interactions after electron impact in 4-substituted cyclohexanones

RT Gray, RJ Spangler, C Djerassi

Index: Gray,R.T. et al. Journal of Organic Chemistry, 1970 , vol. 35, # 5 p. 1525 - 1534

Full Text: HTML

Citation Number: 5

Abstract

It is evident from Scheme I that the lone pair of electrons on the oxygen atom is attributed a leading role in the formation of fragment ion a. Hence, in an attempt to determine the scope and limitations of such a rearrangement process, we have undertaken a mass spectral investigation of a series of other 4-sub-