Tetrahedron Letters

Stereoselective total synthesis of crucigasterins A, B and D through a common intermediate

JN Kumar, B Das

Index: Kumar, Jayprakash Narayan; Das, Biswanath Tetrahedron Letters, 2013 , vol. 54, # 29 p. 3865 - 3867

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Citation Number: 17

Abstract

The first stereoselective total synthesis of the marine-derived antimicrobial amino-alcohols, crucigasterins A, B and D has been accomplished through a common intermediate starting from pent-3-en-1-ol. The method involves the Sharpless asymmetric aminohydroxylation

~76%

~82%

~88%

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[Tetrahedron Letters, , vol. 54, # 29 p. 3865 - 3867]