Alternating ethylene-norbornene copolymerization catalyzed by cationic organopalladium complexes bearing hemilabile bidentate ligands of α-amino-pyridines

YC Lin, KH Yu, SL Huang, YH Liu, Y Wang, ST Liu…

Index: Lin, Ya-Chi; Yu, Kuo-Hsuan; Huang, Shou-Ling; Liu, Yi-Hung; Wang, Yu; Liu, Shiuh-Tzung; Chen, Jwu-Ting Dalton Transactions, 2009 , # 41 p. 9058 - 9067

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Citation Number: 11

Abstract

Cationic methylpalladium complexes with hemilabile bidentate ligands of α-amino-pyridines, in the form of {[R1HNCR2H (o-C6H5N)] Pd (Me)(NCMe)}(BF4)(R1= iPr, tBu, Ar R2= H, Me) have been found to be effective precursors for catalytic copolymerization of ethylene and ...