Synthetic Communications

Carboxylation of arenes

P Menegheli, MC Rezende, C Zucco

Index: Menegheli, Paulo; Rezende, Marcos Caroli; Zucco, Cezar Synthetic Communications, 1987 , vol. 17, # 4 p. 457 - 464

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Citation Number: 18

Abstract

The carboxylation of aromatic rings can be accomplished ... In a variation of this method, we wish to report a simple ... The reaction of an arene with chloral in the presence of ... 2,2-diarylethanes. The molar ratio of AIClg/chloral varies with ... 0.2 was established for systems more reactive than benzene. ... This is also a good value for benzene itself. Less activated ... However, if an oxidant such as hydrogen peroxide is added, a