Inorganica Chimica Acta

Interactions of tertiary phosphines with p-benzoquinones; X-ray structures of [HO (CH 2) 3] 3 P+ C 6 H 2 (O−)(OH)(MeO) and Ph 3 P+ C 6 H 3 (O−)(OH)

DV Moiseev, BO Patrick, BR James, TQ Hu

Index: Moiseev, Dmitry V.; Patrick, Brian O.; James, Brian R.; Hu, Thomas Q. Inorganica Chimica Acta, 2010 , vol. 363, # 13 p. 3569 - 3574

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Citation Number: 10

Abstract

Phosphonium zwitterions of a known type were obtained in high yield via a 1: 1 reaction of p- benzoquinone or methoxy-p-benzoquinone with the tertiary phosphines R3P [R=(CH2) 3OH, Ph, Et, Me] and Ph2MeP, in acetone or benzene at room temperature. In all cases, attack of the P-atom occurs at a C-atom rather than at an O-atom. The products were characterized to various degrees by elemental analysis, 31P {1H}, 1H and 13C NMR ...