Carbohydrate Research

Synthesis of two 3-amino-2, 3-dideoxyhexuronic acid derivatives

D Horton, W Weckerle, B Winter

Index: Horton,D. et al. Carbohydrate Research, 1979 , vol. 70, p. 59 - 73

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Citation Number: 7

Abstract

Abstract Methyl (methyl 3-acetamido-2, 3-dideoxy-α-D-ribo-hexopyranosid) uronate was prepared from methyl 3-acetamido-4O-benzoyl-6-bromo-2, 3, 6-trideoxy-α-D-ribo- hexopyranoside (2) by a sequence or reactions involving photodecom̄position of the 6- azido-4-hydroxyl analog of 2, followed by successive mild hydrolysis of the intermediate imine 8 (to afford the aldehyde 11), oxidation, and esterification. In contrast, mild ...