Side chain impacts on pH??and thermo??responsiveness of tertiary amine functionalized polypeptides

C Xiao, Y Cheng, Y Zhang, J Ding, C He…

Index: Xiao, Chunsheng; Cheng, Yilong; Zhang, Yu; Ding, Jianxun; He, Chaoliang; Zhuang, Xiuli; Chen, Xuesi Journal of Polymer Science, Part A: Polymer Chemistry, 2014 , vol. 52, # 5 p. 671 - 679

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Citation Number: 11

Abstract

ABSTRACT The systemic investigation of the structural impacts of side chains on the pH-and thermo-responsiveness of tertiary amine functionalized poly (l-glutamate) s (TA-PGs) was carried out. The TA-PGs polymers were effectively synthesized by Cu (I)-catalyzed azide- alkyne cycloaddition click reaction of azido tertiary amines with poly (γ-propargyl-l- glutamate)(PPLG). Turbimetric measurements were performed to characterize the pH-and ...