Synthesis and Relaxometric Properties of Gadolinium (III) Complexes of New Triazine??Based Polydentate Ligands

…, M Benzi, F Kielar, M Botta, C Cavallotti…

Index: Tei, Lorenzo; Benzi, Marina; Kielar, Filip; Botta, Mauro; Cavallotti, Camilla; Giovenzana, Giovanni Battista; Aime, Silvio Helvetica Chimica Acta, 2009 , vol. 92, # 11 p. 2414 - 2426

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Citation Number: 7

Abstract

Abstract Two new derivatives based on an s-triazine structural motif were synthesized by attaching two 2, 2′-hydrazinylidenebis [acetic acid] moieties to the triazine ring to reach an overall heptadenticity for the complexation of lanthanide (III) cations. The remaining reactive site was exploited for the substitution with a functionizable amino group (see H 4 L1) and a lipophilic moiety (see H 4 L2). Luminescence-lifetime determinations revealed the ...