Synthesis and pyrolytic behaviour of thiazolidin-2-one 1, 1-dioxides

R áAlan Aitken, DP Armstrong, RHB Galt…

Index: Aitken, R. Alan; Armstrong, David P.; Galt, Ronald H. B.; Mesher, Shaun T. E. Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 14 p. 2139 - 2145

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Citation Number: 21

Abstract

Four examples of the chiral thiazolidin-2-one 1, 1-dioxides 5 have been prepared by reaction of the appropriate amino alcohols 11 with CS in aqueous sodium hydroxide to give the thiazolidine-2-thiones 12, followed by oxidation with KMnO under phase-transfer conditions in the presence of benzoic acid, either directly