Synthesis of novel sulfonyl-stabilized phosphorus ylides, and the kinetics and mechanism of their conventional and flash vacuum pyrolysis reactions

…, NA Al-Awadi, OME El-Dusouqui

Index: Al-Bashir, Rasha F.; Al-Awadi, Nouria A.; El-Dusouqui, Osman M.E. Canadian Journal of Chemistry, 2005 , vol. 83, # 9 p. 1543 - 1553

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Citation Number: 6

Abstract

Nine substituted sulfonyl-stabilized phosphorus ylides were prepared by treating their intermediate ylide analogues with phenylmethanesulfonyl fluoride. The stoichiometric ratio of the reactants for each preparation needed to be adjusted according to the basicity of each ylide intermediate. The nine ylide compounds were then subjected to conventional (sealed- tube) gas-phase pyrolysis at 470 545 K. The pyrolytic reactions were homogeneous and ...