Chlorine-water Oxidation of Some α-Methylsulfonyl Sulfides

WR Hardstaff, RF Langler, J Leahy…

Index: Hardstaff,W.R. et al. Canadian Journal of Chemistry, 1975 , vol. 53, p. 2664 - 2670

Full Text: HTML

Citation Number: 12

Abstract

An examination of the chlorination of phenylmethy), diphenylmethyl, and triphenylmethyl methylsulfonyl sulfides (1, 2, and 3) in aqueous acetic acid has provided indirect evidence for Pummerer rearrangement during the chlorination of an α-methylsulfonyl sulfinyl chloride. The results are discussed from both mechanistic and synthetic standpoints.

Chemoselective mono halogenation of β-keto-sulfones using po...

[Suryakiran; Prabhakar; Srikanth Reddy; Chinni Mahesh; Rajesh; Venkateswarlu Tetrahedron Letters, 2007 , vol. 48, # 5 p. 877 - 881]

Chlorination of Dimethyl Sulfide and Some of Its Derivatives...

[Truce et al. Journal of the American Chemical Society, 1952 , vol. 74, p. 3594,3597]

Mechanisms in the chlorinolysis of sulfinyl chlorides

[Ahern, Terence Patrick; Haley, Michael Francis; Langler, Richard Francis; Trenholm, June Ellen Canadian Journal of Chemistry, 1984 , vol. 62, p. 610 - 614]

Sulfonyl esters 3. The formation of sulfone-sulfonates in th...

[Baum, James Clayton; Durkin, Kathleen Anne; Precedo, Laura; O'Blenes, Stacy Brian; Goehl, John Edward; et al. Canadian Journal of Chemistry, 1991 , vol. 69, # 12 p. 2127 - 2135]