Reactions of bi (cyclophosphazenes) with sodium alkoxides or aryl oxides

HR Allcock, MS Connolly, PJ Harris

Index: Allcock, Harry R.; Connolly, Mark S.; Harris, Paul J. Journal of the American Chemical Society, 1982 , vol. 104, # 9 p. 2482 - 2490

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Citation Number: 13

Abstract

Abstract: Bi (cyc1ophosphazenes)(2) react with nucleophiles such as sodium trifluoroethoxide or sodium phenoxide by two alternative pathways-(a) with cleavage of the PP ring linkage unit and cleavage of P-Cl bonds to yield organocyclotriphosphazenes (3) or (b) by cleavage of P-CI bonds without rupture of PP bonds to give organobi (cyc1ophosphazenes)(6). These latter species eventually undergo PP bond scission with ...