Persulfonium salts: the reaction of a difluoropersulfurane with Lewis acids

RS Michalak, JC Martin

Index: Michalak, Ronald S.; Martin, J. C. Journal of the American Chemical Society, 1980 , vol. 102, # 18 p. 5921 - 5923

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Citation Number: 12

Abstract

4-t-BuN= PF, to be downfield of the equatorial PF signal for the corresponding electrically neutral fluorophosphoranes (1O-P-5), again showing an order of chemical shifts opposite to that predicted from charge alone. I0 The peak for fluorines on phosphorus is very broad because of PF5-PF6-exchange and is centered at 68.2 ppm. The mass spectrum of 3 shows a large peak (25% of the base intensity) at m/e 535 for M+-F, presumably the persulfonium ...