Preparation of 1-phenylcyclohexa-2, 5-diene-1-carboxylates and their use in free-radical mediated syntheses

PA Baguley, LV Jackson, JC Walton

Index: Baguley, Paul A.; Jackson, Leon V.; Walton, John C. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 304 - 309

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Citation Number: 21

Abstract

Synthetic routes to pure 1-phenylcyclohexa-2, 5-diene-1-carboxylic acid and derived esters were developed. Esters containing appropriately unsaturated side chains generated the corresponding alkenyl radicals and hence gave good yields of 5-exo ring closure products ...