Organic photochemistry with 6.7-eV photons: rigid homoallylic alcohols. An inverse Norrish type II rearrangement

J Studebaker, R Srinivasan, JA Ors…

Index: Studebaker, Joel; Srinivasan, R.; Ors, Jose A.; Baum, Thomas Journal of the American Chemical Society, 1980 , vol. 102, # 22 p. 6872 - 6874

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Abstract

2 4 at 185 nm in pentane solution gave mixtures of isomeric aldehydes which were isolated by GC and identified by comparison of their spectra to those of authentic material. Both 2 and 3 gave rise to the same pair of unsaturated aldehydes 6 and 710* 11 while 4 and fCHO fCHO