Chemical transformations of ethyl 3, 5-dicyano-2, 4, 4, 6-tetramethyl-1, 4-dihydro-1-pyridyl acetate, sythesis of a new N-vinyl monomer

J Paleček, M Pavlík, J Kuthan

Index: Palecek, Jaroslav; Pavlik, Manfred; Kuthan, Josef Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 2 p. 617 - 622

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Abstract

Abstract Ethoxycarbonyl group in the title compound I undergoes regioselective functional transformations to give the amide II and the carboxylic acid III. Reduction with lithium aluminium hydride gave the alcohol V whose p-toluenesulfonate was converted directly or via 2-iodoethyl derivative VIII into the N-vinyl monomer IX. Absorption molecular spectra of the synthesized compounds I-IX, as well as their fragmentation by electron impact, are ...