Reactions of carbocations with unsaturated hydrocarbons: Electrophilic alkylation or hydride abstraction?

H Mayr, G Lang, AR Ofial

Index: Bethell, Donald; Clare, Peter N.; Hare, Gerard J. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1889 - 1894

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Citation Number: 81

Abstract

... J. Am. Chem. Soc. ... figure Figure 2 Comparison of the reactions of benzhydrylium ions 1 + with hydride donors and π-nucleophiles (CH 2 Cl 2 , 20 °C). Table 4. Nucleophilicity Parameters for Hydride Donors. hydride donor, N, s. cycloheptatriene (2), 0.52, (0.97) a. ...