Monovalent K, Cs, Tl, and Ag Nitrosodicyanomethanides: Completely Different 3D Networks with Useful Properties of Luminescent Materials and Nonelectric Sensors …

…, N Gerasimchuk, R Biagioni, KV Domasevitch

Index: Glover, Garrett; Gerasimchuk, Nikolay; Biagioni, Richard; Domasevitch, Konstantin V. Inorganic Chemistry, 2009 , vol. 48, # 6 p. 2371 - 2382

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Citation Number: 14

Abstract

We report the preparation, spectroscopic properties, and structures of three new heavy metal complexes (Ag, Cs, and Tl (I)) of nitrosodicyanomethanide in which the anion acts as a multidentate bridging ligand. Ag {ONC (CN) 2} demonstrates years-long stability toward visible light, which is a very convenient property in view of the compound's color change/darkening only after exposure to gaseous H2, NO, CO, C2H2, and C2H4. The ...